Item type |
学術雑誌論文 / Journal Article(1) |
公開日 |
2024-07-01 |
タイトル |
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言語 |
en |
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タイトル |
Electrocatalytic Oxidation of Primary Alcohols at the Triple-Phase Boundary in an Anion-Exchange Membrane Reactor with Nickel, Cobalt, and Iron Catalysts |
言語 |
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言語 |
eng |
キーワード |
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主題 |
electrosynthesis, anion-exchange membrane reactor, electrocatalytic oxidation, oxyhydroxide, triple-phase boundary(en) |
資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
著者 |
Yuka, Furutani
en |
Yuka, Furutani
Department of Chemistry and Life Science, Yokohama National University
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Search repository
Yugo, Shimizu
en |
Yugo, Shimizu
Department of Chemistry and Life Science, Yokohama National University
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Search repository
Juri, Harada
en |
Juri, Harada
Department of Chemistry and Life Science, Yokohama National University
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Search repository
Yusuke, Muto
en |
Yusuke, Muto
Department of Chemistry and Life Science, Yokohama National University
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Search repository
Akizumi, Yonezawa
en |
Akizumi, Yonezawa
Department of Chemistry and Life Science, Yokohama National University
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Search repository
Shoji, Iguchi
Naoki, Shida
ORCID
0000-0003-0586-1216
en |
Naoki, Shida
Department of Chemistry and Life Science, Yokohama National University
Institute of Advanced Sciences, Yokohama National University
PRESTO, Japan Science and Technology Agency (JST)
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Search repository
Mahito, Atobe
ORCID
0000-0002-3173-3608
en |
Mahito, Atobe
Department of Chemistry and Life Science, Yokohama National University
Institute of Advanced Sciences, Yokohama National University
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Search repository
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抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
Transition metals, such as nickel (Ni), cobalt (Co), and iron (Fe), exhibit catalytic activity for electrochemical oxidation under basic conditions. In this study, we demonstrate the highly selective electrochemical oxidation of primary alcohols to aldehydes using Ni, Co, and Fe catalysts in an anion-exchange membrane (AEM) reactor. Our findings indicate that non-noble metal catalysts can be utilized for the electrocatalytic oxidation of primary alcohols by leveraging basic conditions that do not corrode these metals. In addition, we prepared binary metal alloys and oxide catalysts and investigated their catalytic abilities for alcohol oxidation. The results demonstrate that controlling the oxygen evolution reaction potential through the composition ratio of the binary catalyst and avoiding interference with the desired alcohol oxidation are crucial for increasing the yield of the oxidation products. Furthermore, despite the basic nature of the reaction sites, the electrocatalytic oxidation of primary alcohols selectively yielded the corresponding aldehydes, which was attributed to the unique triple-phase interfacial reaction sites in the AEM reactor. |
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言語 |
en |
書誌情報 |
en : ACS Catalysis
巻 14,
号 11,
p. 8922-8929,
ページ数 8,
発行日 2024-05-26
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ISSN |
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収録物識別子タイプ |
EISSN |
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収録物識別子 |
21555435 |
書誌レコードID |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA12599706 |
DOI |
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関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1021/acscatal.4c01097 |
権利 |
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言語 |
en |
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権利情報Resource |
https://pubs.acs.org/page/copyright/journals/posting_policies.html |
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権利情報 |
This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © 2024 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-IICZNPXUZEPIH9F6V3DQ . |
著者版フラグ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
出版者 |
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出版者 |
American Chemical Society |