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  1. 05 工学研究院・理工学府・理工学部
  2. 5-1 学術雑誌論文

Boron-carbon-silicon film chemical vapor deposition by boron trichloride, dichlorosilane and monomethylsilane gases

http://hdl.handle.net/10131/0002001141
http://hdl.handle.net/10131/0002001141
e6fd8266-a77c-4da3-b1d8-fdba7126cb54
名前 / ファイル ライセンス アクション
本文へのアクセスはこちら 本文へのアクセスはこちら
Item type 学術雑誌論文 / Journal Article(1)
公開日 2024-08-30
タイトル
タイトル Boron-carbon-silicon film chemical vapor deposition by boron trichloride, dichlorosilane and monomethylsilane gases
言語 en
言語
言語 eng
キーワード
主題 Chemical vapor deposition; Carbon incorporation; Boron trichloride; Dichlorosilane; Monomethylsilane(en)
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
著者 Otani, Mana

× Otani, Mana

en Otani, Mana
Dept Chem Applicat, Yokohama National University

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Muroi, Mitsuko

× Muroi, Mitsuko

en Muroi, Mitsuko
Dept Chem Applicat, Yokohama National University

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Habuka, Hitoshi

× Habuka, Hitoshi

ORCID 0000-0001-9931-5915
e-Rad_Researcher 40323927

en Habuka, Hitoshi
Dept Chem Applicat, Yokohama National University

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抄録
内容記述タイプ Abstract
内容記述 A boron-carbon-silicon film was formed by an atmospheric pressure chemical vapor deposition method using a gas mixture of boron trichloride, dichlorosilane and monomethylsilane in ambient hydrogen at 800-1000 degrees C. The boron, carbon and silicon concentrations in the obtained film were about 15-30 %, 0-10 % and 50-80 %, respectively. With the increasing monomethylsilane gas flow rate, the carbon and silicon concentrations in the obtained film increased and decreased, respectively. In the obtained film, various chemical bonds between the boron, carbon and silicon existed, except for the carbon-carbon bond. The following conclusions were obtained. (i) The carbon atoms existing at the surface have a chemical bond with the boron atoms, but not with the carbon and silicon atoms. (ii) The surface intermediate compound of boron chloride helps incorporating the carbon, while that of dichlorosilane does not. (iii) The etching by the hydrogen chloride gas significantly influenced the film formation process at higher than 900 degrees C.
言語 en
書誌情報 en : Surface and Coatings Technology

巻 448, ページ数 7, 発行日 2022-10-05
ISSN
収録物識別子タイプ PISSN
収録物識別子 02578972
DOI
識別子タイプ DOI
関連識別子 https://doi.org/10.1016/j.surfcoat.2022.128936
著者版フラグ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
出版者
出版者 Elsevier Science SA
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