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Synthesis and combustion inhibition efficiency of iron short-chain perfluorocarboxylates
http://hdl.handle.net/10131/00013441
http://hdl.handle.net/10131/000134413901a5f9-800c-404d-8fa5-f992f55dd66a
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
Synthesis and combustion inhibition efficiency of iron short-chain perfluorocarboxylates.pdf (1.6 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2020-10-13 | |||||
| タイトル | ||||||
| タイトル | Synthesis and combustion inhibition efficiency of iron short-chain perfluorocarboxylates | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Iron complex | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Short-chain perfluorocarboxylato complex | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Fire suppression | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Minimum extinction concentration | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Phosphorus-free | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Flame inhibition | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | @Powder fire-extinguishing agent | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Koshiba, Yusuke
× Koshiba, Yusuke× Tsunokuma, Yuji× Ohtani, Hideo |
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| 著者所属 | ||||||
| 値 | Department of Materials Science and Chemical Engineering, Faculty of Engineering, Yokohama National University | |||||
| 著者所属 | ||||||
| 値 | Graduate School of Environmental and Information Sciences, Yokohama National University | |||||
| 著者所属 | ||||||
| 値 | Department of Safety Management, Faculty of Environmental and Information Sciences | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | This study reports an experimental exploration of the combustion inhibition efficiency of iron short-chain perfluorocarboxylates, namely, iron trifluoroacetate (FeTFA) and iron pentafluoropropionate (FePFP). The aim is to develop a new phosphor-free fire-extinguishing agent. The synthesized FeTFA and FePFP were characterized by ultraviolet–visible spectroscopy, Fourier-transform infrared spectroscopy, X-ray fluorescence measurements, and fast-atom bombardment mass spectrometry. The FeTFA and FePFP ligands (i) coordinate with the iron ions in bridging form via carboxylate oxygens, (ii) contain no Cl−, and (iii) are hexanuclear complexes with chemical formulas of C₁₈F₂₇O₂₂Fe₆ and C₂₇F₄₅O₂₂Fe₆, respectively. Suppression trials and thermogravimetric measurements revealed that (i) both FeTFA and FePFP have higher combustion inhibition ability at lower suppressant concentrations than ammonium dihydrogen phosphate (an active component in conventional fire-extinguishing agents), (ii) FePFP is remarkably more inhibition-efficient than FeTFA, and (iii) neither FeTFA nor FePFP hinder cellulose pyrolysis and char combustion in the condensed phase. Thermogravimetry–mass spectrometry measurements confirmed that (i) the main gas-phase decomposition product of FeTFA and FePFP is CF₃, and (ii) FePFP is a better CF₃ generator than FeTFA. The different inhibition abilities of the two complexes were attributed to their different CF₃ generation abilities and eases of decomposing the complex. | |||||
| 書誌情報 |
Fire safety journal 巻 118, p. 103224, 発行日 2020-09-25 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0379-7112 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA11526059 | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | info:doi/10.1016/j.firesaf.2020.103224 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| 出版者 | ||||||
| 出版者 | Elsevier | |||||
| 関係URI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1016/j.firesaf.2020.103224 | |||||
| 関連名称 | https://doi.org/10.1016/j.firesaf.2020.103224 | |||||
