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  1. 08 先端科学高等研究院
  2. 8-1 学術雑誌論文

Niobium-added titanium oxides powders as non-noble metal cathodes for polymer electrolyte fuel cells – Electrochemical evaluation and effect of added amount of niobium

http://hdl.handle.net/10131/00012888
http://hdl.handle.net/10131/00012888
1aca249d-b298-47b4-98a8-0e847fcc34c4
名前 / ファイル ライセンス アクション
IntJHydroEne_Manuscript_190730.pdf IntJHydroEne_Manuscript_190730 (1.2 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2020-02-10
タイトル
タイトル Niobium-added titanium oxides powders as non-noble metal cathodes for polymer electrolyte fuel cells – Electrochemical evaluation and effect of added amount of niobium
言語
言語 eng
キーワード
主題Scheme Other
主題 Niobium-added titanium oxides
キーワード
主題Scheme Other
主題 Oxygen reduction reaction
キーワード
主題Scheme Other
主題 Polymer electrolyte fuel cells
キーワード
主題Scheme Other
主題 Non-platinum cathode
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
著者 Ishihara, Akimitsu

× Ishihara, Akimitsu

WEKO 36447

Ishihara, Akimitsu

Search repository
Arao, Masazumi

× Arao, Masazumi

WEKO 36448

Arao, Masazumi

Search repository
Matsumoto, Masashi

× Matsumoto, Masashi

WEKO 36449

Matsumoto, Masashi

Search repository
Tokai, Tsubasa

× Tokai, Tsubasa

WEKO 36450

Tokai, Tsubasa

Search repository
Nagai, Takaaki

× Nagai, Takaaki

WEKO 36451

Nagai, Takaaki

Search repository
Kuroda, Yoshiyuki

× Kuroda, Yoshiyuki

WEKO 36456
e-Rad 50638640

Kuroda, Yoshiyuki

Search repository
Matsuzawa, Koichi

× Matsuzawa, Koichi

WEKO 36457
e-Rad 80500743

Matsuzawa, Koichi

Search repository
Imai, Hideto

× Imai, Hideto

WEKO 36458

Imai, Hideto

Search repository
Mitsushima, Shigenori

× Mitsushima, Shigenori

WEKO 36446
e-Rad 70323938

Mitsushima, Shigenori

Search repository
Ota, Ken-ichiro

× Ota, Ken-ichiro

WEKO 36459
e-Rad 30011216

Ota, Ken-ichiro

Search repository
著者所属
Institute of Advanced Sciences, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501 Japan
著者所属
Device Analysis Department, NISSAN ARC Ltd., 1 Natsushima-cho, Yokosuka 237-0061, Japan
著者所属
Device Analysis Department, NISSAN ARC Ltd., 1 Natsushima-cho, Yokosuka 237-0061, Japan
著者所属
Green Hydrogen Research Center, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501 Japan
著者所属
Green Hydrogen Research Center, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501 Japan
著者所属
Green Hydrogen Research Center, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501 Japan
著者所属
Green Hydrogen Research Center, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501 Japan
著者所属
Device Analysis Department, NISSAN ARC Ltd., 1 Natsushima-cho, Yokosuka 237-0061, Japan
著者所属
Institute of Advanced Sciences, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501 Japan / Green Hydrogen Research Center, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501 Japan
著者所属
Institute of Advanced Sciences, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501 Japan
抄録
内容記述タイプ Abstract
内容記述 An appropriate evaluation of oxide-based compound powders as non-platinum cathodes for polymer electrolyte fuel cells is required to investigate the active sites of oxide-based cathodes for the oxygen reduction reaction. A mixture of carbon black powder as an electro-conductive material with oxide catalysts that had low electrical conductivity was attempted to evaluate the oxygen reduction reaction (ORR) activity. An appropriate mixture of carbon black and the oxide catalysts let to the electrochemical activation of the oxide surface by the formation of electron conduction networks. Using the carbon black mixture, the niobium-added titanium oxides heat-treated at 700 °C for 10 min under Ar containing 4% hydrogen without carbon materials were focused on to reveal the dependence of ORR activity on the added amount of niobium. The ORR activity of the niobium-added titanium oxides increased the Nb mole percentage from 0 to 20. This was due to the increase in the ratio of the Ti3+/(Ti4++Ti3+), and suggests that the active sites were Ti3+ and/or oxygen vacancies in the anatase phase. On the other hand, although the ratio of the Ti3+/(Ti4++Ti3+) of the oxide with an Nb mole percentage of 30 was almost twice as that with an Nb mole percentage of 20, the ORR activities were almost the same. This might be responsible for the deposition of the amorphous phase composed of Nb2O5, which consisted of a thin layer on the surface of the oxide particles and had low ORR activity.
書誌情報 International Journal of Hydrogen Energy

巻 45, 号 8, p. 5438-5448, 発行日 2020-02-14
ISSN
収録物識別子タイプ ISSN
収録物識別子 03603199
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA00680410
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 info:doi/10.1016/j.ijhydene.2019.08.217
出版者
出版者 Elsevier
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