{"created":"2023-06-20T15:08:11.565239+00:00","id":3927,"links":{},"metadata":{"_buckets":{"deposit":"badb57df-5715-4b76-ab62-8adccaa3bfeb"},"_deposit":{"created_by":3,"id":"3927","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3927"},"status":"published"},"_oai":{"id":"oai:ynu.repo.nii.ac.jp:00003927","sets":["495:496"]},"author_link":["17426","17422","17423","17425","17424"],"item_2_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2007-06","bibliographicIssueDateType":"Issued"},"bibliographic_titles":[{"bibliographic_title":"Proceedings of the 26th International Conference on Thermoelectrics (ICT2007) 3-7 June"}]}]},"item_2_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We have prepared polysrystalline specimens of Y doped ＄Ca_{3}Co_{4}O_{9}＄ using a conventional solid-state reaction method, and investgated the Y substitution effect on the thermoelectric and magnetic properities. The valence state of Co ions in ＄[(ca_{1-x}Y_x)_{2}CoO_{3}]_{0.62}CoO_{2}(0 leqq x leqq 0.04)＄ has been clarified as ＄Co^{3.2+}＄ in ＄CoO_{2}＄ sheet and ＄Co^{3.6+}＄ in RS-type BL, respectively. In addition,both a broad minimum at around 100K ＄(T_{SDW}^{on})＄ and a broad maximum between ＄T_{SS}^{end}＄ and ＄T_{SS}^{on}＄ in the ρ(T) curve correspond to two magnetic transitions,where ＄T_{SS}^{end}＄ and ＄T_{SS}^{on}＄ could correspond to the spin-state transition of Co ions in the ＄CoO_{2}＄ sheet and in the RS-type BL, respectively. Furthermore,in x= 0.02 and 0.04 samples,the seebeck coeddicient at 800K, show the highest value (S = 176μ V/K) .Therefore, Y doped ＄Ca_{3}Co_{4}O_{9}＄ are potential candidates for the practical use of thermoelectric power generations.","subitem_description_type":"Abstract"}]},"item_2_full_name_2":{"attribute_name":"著者(ヨミ)","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{"name":"ナカツガワ, ヒロシ"}]}]},"item_2_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{}]}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"IEEE"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1109/ICT.2007.4569404","subitem_relation_type_select":"DOI"}}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"10942734 ","subitem_source_identifier_type":"ISSN"}]},"item_2_text_4":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Yokohama National University"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nakatsugawa, Hiroshi"}],"nameIdentifiers":[{"nameIdentifier":"17422","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Jeong, H. M."}],"nameIdentifiers":[{"nameIdentifier":"17423","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nagasawa, K."}],"nameIdentifiers":[{"nameIdentifier":"17424","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-09-16"}],"displaytype":"detail","filename":"ICT2007-Nakatsugawa.pdf","filesize":[{"value":"471.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ICT2007-Nakatsugawa.pdf","url":"https://ynu.repo.nii.ac.jp/record/3927/files/ICT2007-Nakatsugawa.pdf"},"version_id":"94f20470-9042-46c1-9b32-0bcfc9d41e18"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Thermoelectric properties and crystal structures in Y doped ＄Ca_{3}Co_{4}O_{9}＄","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Thermoelectric properties and crystal structures in Y doped ＄Ca_{3}Co_{4}O_{9}＄"}]},"item_type_id":"2","owner":"3","path":["496"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-12-14"},"publish_date":"2009-12-14","publish_status":"0","recid":"3927","relation_version_is_last":true,"title":["Thermoelectric properties and crystal structures in Y doped ＄Ca_{3}Co_{4}O_{9}＄"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T19:38:51.784041+00:00"}