{"created":"2023-06-20T15:07:57.936497+00:00","id":3662,"links":{},"metadata":{"_buckets":{"deposit":"f022eb51-6cd3-47de-ae09-14ecedd0cf94"},"_deposit":{"created_by":3,"id":"3662","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"3662"},"status":"published"},"_oai":{"id":"oai:ynu.repo.nii.ac.jp:00003662","sets":["495:496"]},"author_link":["15698","15697","15701","15703","15700","15702","15699"],"item_2_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2005-02-02","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"263","bibliographicPageStart":"258","bibliographicVolumeNumber":"140","bibliographic_titles":[{"bibliographic_title":"Journal of Power Sources"}]}]},"item_2_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_description_42":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"postprint","subitem_description_type":"Other"}]},"item_2_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"For practical use of molten carbonate fuel cells (MCFCs), Ni shorting due to NiO cathode dissolution during high-pressure operation is still a serious problem. The molten carbonate electrolyte should be more basic in order to reduce the NiO cathode solubility. In order to obtain a lower NiO solubility, the solubility of La oxide was investigated in the Li/Na/K and the Li/Na eutectic carbonates and the effect of the La oxide addition to the molten carbonate on the NiO solubility has also been investigated. The stable phase of La oxide in molten carbonate was found to be La2O2CO3 under P-CO2/P-O2 = 0.7/0.3 atm at 923 K. The solubility of NiO significantly decreased due to La additive in the acid dissolution region that is the operating condition for the MCFCs. The order of the base comparative index on the NiO solubility in the molten carbonate was La much greater than Ca = Sr > Li > Na > K. (C) 2004 Elsevier B.V. All rights reserved.","subitem_description_type":"Abstract"}]},"item_2_full_name_2":{"attribute_name":"著者(ヨミ)","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{"name":"オオタ, ケンイチロウ"}]}]},"item_2_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{}],"names":[{}]}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier Science B.V."}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1016/j.jpowsour.2004.08.041","subitem_relation_type_select":"DOI"}}]},"item_2_rights_14":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"NOTICE: This is the author's version of a work accepted for publication by Elsevier. Changes resulting from the publishing process, including peer review, editing, corrections, structual formatting and other quality control mechanisms , may not be reflected in this document. Changes may have been to this work since it was submitted for publication."}]},"item_2_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00705373","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"03787753","subitem_source_identifier_type":"ISSN"}]},"item_2_text_4":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Yokohama Natl Univ, Dept Energy & Safety Engn, Hodogaya Ku, Yokohama, Kanagawa 2408501, Japan"},{"subitem_text_value":"横浜国立大学　工学研究院　機能の創生　過程の機能と安全分野"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Matsuzawa, K."}],"nameIdentifiers":[{"nameIdentifier":"15697","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mizusaki, T."}],"nameIdentifiers":[{"nameIdentifier":"15698","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mitsushima, S."}],"nameIdentifiers":[{"nameIdentifier":"15699","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kamiya, N."}],"nameIdentifiers":[{"nameIdentifier":"15700","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ota, Ken-ichiro"}],"nameIdentifiers":[{"nameIdentifier":"15701","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-09-16"}],"displaytype":"detail","filename":"ISI-000226707500006-01.pdf","filesize":[{"value":"265.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ISI-000226707500006-01.pdf","url":"https://ynu.repo.nii.ac.jp/record/3662/files/ISI-000226707500006-01.pdf"},"version_id":"da4ae1c9-fb59-4e1e-be8e-f8c182ae7516"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"MCFC","subitem_subject_scheme":"Other"},{"subitem_subject":"molten carbonate","subitem_subject_scheme":"Other"},{"subitem_subject":"NiO solubility","subitem_subject_scheme":"Other"},{"subitem_subject":"electrolyte","subitem_subject_scheme":"Other"},{"subitem_subject":"additive","subitem_subject_scheme":"Other"},{"subitem_subject":"lanthanum","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"The effect of La oxide additive on the solubility of NiO in molten carbonates","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"The effect of La oxide additive on the solubility of NiO in molten carbonates"}]},"item_type_id":"2","owner":"3","path":["496"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-06-07"},"publish_date":"2007-06-07","publish_status":"0","recid":"3662","relation_version_is_last":true,"title":["The effect of La oxide additive on the solubility of NiO in molten carbonates"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T17:59:04.008658+00:00"}