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Conversion of Cellobiose to Formic Acid as a Biomass-Derived Renewable Hydrogen Source Using Solid Base Catalysts
http://hdl.handle.net/10131/0002001356
http://hdl.handle.net/10131/00020013567993e08a-9c22-447f-b8fb-9965dfc571c2
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
ChemistryOpen - 2024 - Yoshiki - Conversion of Cellobiose to Formic Acid as a Biomass‐Derived Renewable Hydrogen Source.pdf (3.3 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||||
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| 公開日 | 2024-10-22 | |||||||||||||||
| タイトル | ||||||||||||||||
| タイトル | Conversion of Cellobiose to Formic Acid as a Biomass-Derived Renewable Hydrogen Source Using Solid Base Catalysts | |||||||||||||||
| 言語 | en | |||||||||||||||
| 言語 | ||||||||||||||||
| 言語 | eng | |||||||||||||||
| 資源タイプ | ||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||
| 資源タイプ | journal article | |||||||||||||||
| アクセス権 | ||||||||||||||||
| アクセス権 | open access | |||||||||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||||||
| 著者 |
Yoshiki, Ikuto
× Yoshiki, Ikuto
× Takagaki, Atsushi
ORCID
0000-0002-7829-3451
× Song, Jun, Tae
ORCID
0000-0003-1047-6152
× Watanabe, Motonori
ORCID
0000-0003-3621-4361
× Ishihara, Tatsumi
ORCID
0000-0002-7434-3773
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| 抄録 | ||||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||||
| 内容記述 | Formic acid is considered a promising hydrogen carrier. Biomass-derived formic acid can be obtained by oxidative decomposition of sugars. This study explored the production of formic acid from cellobiose, a disaccharide consisting of d-glucose linked by β-glycosidic bonds using heterogeneous catalysts under mild reaction conditions. The use of alkaline earth metal oxide solid base catalysts like CaO and MgO in the presence of hydrogen peroxide could afford formic acid from cellobiose at 343 K. While CaO gave 14 % yield of formic acid, the oxide itself was converted to a harmful metal peroxide, CaO2 after the reaction. In contrast, MgO could produce formic acid without the formation of the metal peroxide. The difficulty in selectively synthesizing formic acid from cellobiose using these solid base catalysts was due to the poor conversion of cellobiose to glucose. Using a combination of solid acid and base catalysts, a high formic acid yield of 33 % was obtained under mild reaction conditions due to the quantitative hydrolysis of cellobiose to glucose by a solid acid followed by the selective decomposition of glucose to formic acid by a solid base. | |||||||||||||||
| 言語 | en | |||||||||||||||
| 内容記述 | ||||||||||||||||
| 内容記述タイプ | Other | |||||||||||||||
| 内容記述 | Acknowledgments This work was supported by a Grand-in-Aid for Challenging Research (Exploratory) (No. 21K18853) of JSPS, Japan. |
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| 言語 | en | |||||||||||||||
| 書誌情報 |
en : ChemistryOpen 巻 Early Access, 発行日 2024-10-07 |
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| ISSN | ||||||||||||||||
| 収録物識別子タイプ | EISSN | |||||||||||||||
| 収録物識別子 | 21911363 | |||||||||||||||
| DOI | ||||||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||
| 関連識別子 | https://doi.org/10.1002/open.202400079 | |||||||||||||||
| 権利 | ||||||||||||||||
| 言語 | en | |||||||||||||||
| 権利情報Resource | https://creativecommons.org/licenses/by/4.0/ | |||||||||||||||
| 権利情報 | Creative Commons Attribution 4.0 International | |||||||||||||||
| 著者版フラグ | ||||||||||||||||
| 出版タイプ | VoR | |||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||
| 出版者 | ||||||||||||||||
| 出版者 | Wiley-VCH GmbH | |||||||||||||||
| 助成情報 | ||||||||||||||||
| 助成機関名 | 独立行政法人日本学術振興会 | |||||||||||||||
| 言語 | ja | |||||||||||||||
| 助成機関名 | Japan Society for the Promotion of Science | |||||||||||||||
| 言語 | en | |||||||||||||||
| 言語 | ja | |||||||||||||||
| プログラム情報 | 科学研究費助成事業 | |||||||||||||||
| 研究課題番号URI | https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-21K18853/ | |||||||||||||||
| 研究課題番号 | JP21K18853 | |||||||||||||||
| 研究課題番号タイプ | JGN | |||||||||||||||
| 研究課題名 | メカノキャタリシスによるリグノセルロースの低分子化・一括合成 | |||||||||||||||
| 言語 | ja | |||||||||||||||
