{"created":"2024-10-07T01:49:16.185070+00:00","id":2001314,"links":{},"metadata":{"_buckets":{"deposit":"0a08d8a3-d87f-42fb-8862-6d3142e59f1f"},"_deposit":{"created_by":17,"id":"2001314","owner":"17","owners":[17],"pid":{"revision_id":0,"type":"depid","value":"2001314"},"status":"published"},"_oai":{"id":"oai:ynu.repo.nii.ac.jp:02001314","sets":["1006:1009","495:496"]},"author_link":[],"item_1724376541206":{"attribute_name":"item_1724376541206","attribute_value_mlt":[{"subitem_award_numbers":{"subitem_award_number":"JP21H04698, JP24H02204, JPMJCR21O6, JPMXP1121467561, JPMJAP2313, JPMJPF2016, 52172245, 2023G028","subitem_award_uri":"https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-21H04698/ , https://kaken.nii.ac.jp/ja/grant/KAKENHI-PLANNED-24H02204/ , https://projectdb.jst.go.jp/grant/JST-PROJECT-21467943/ , https://projectdb.jst.go.jp/grant/JST-PROJECT-20355245/ ,"},"subitem_award_titles":[{"subitem_award_title":"アニオンレドックスの可逆性を支配する原理解明と革新的蓄電池材料設計への応用","subitem_award_title_language":"ja"},{"subitem_award_title":"イオン渋滞学に基づく新物質創製と機能開拓","subitem_award_title_language":"ja"},{"subitem_award_title":"水を基軸とする未踏蓄電機能材料の開拓","subitem_award_title_language":"ja"},{"subitem_award_title":"データ創出・活用型マテリアル研究開発プロジェクト","subitem_award_title_language":"ja"},{"subitem_award_title":"Adopting Sustainable Partnerships for Innovative Research Ecosystem","subitem_award_title_language":"en"},{"subitem_award_title":"先進蓄電池研究開発拠点","subitem_award_title_language":"en"},{"subitem_award_title":"National Natural Science Foundation of China (Grant Number 52172245)","subitem_award_title_language":"en"},{"subitem_award_title":"approval of the Photon Factory Program Advisory Committee (proposal number 2023G028)","subitem_award_title_language":"en"}],"subitem_funder_identifiers":{"subitem_funder_identifier":"1025","subitem_funder_identifier_type":"e-Rad_funder","subitem_funder_identifier_type_uri":"https://www.e-rad.go.jp/datasets/files/haibunkikan.csv"},"subitem_funder_names":[{"subitem_funder_name":"日本学術振興会","subitem_funder_name_language":"ja"},{"subitem_funder_name":"科学技術振興機構","subitem_funder_name_language":"ja"},{"subitem_funder_name":"文部科学省","subitem_funder_name_language":"ja"},{"subitem_funder_name":"National Natural Science Foundation of China","subitem_funder_name_language":"en"},{"subitem_funder_name":"高エネルギー加速器研究機構","subitem_funder_name_language":"ja"}],"subitem_funding_stream_identifiers":{"subitem_funding_stream_identifier":"JP21H04698, JP24H02204, JPMJCR21O6, JPMXP1121467561, JPMJAP2313, JPMJPF2016, 52172245, 2023G028","subitem_funding_stream_identifier_type":"JGN_fundingStream"}}]},"item_2_biblio_info_8":{"attribute_name":"bibliographic_information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2024-09-24","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"18","bibliographicNumberOfPages":"10","bibliographicPageEnd":"8691","bibliographicPageStart":"8682","bibliographicVolumeNumber":"36","bibliographic_titles":[{"bibliographic_title":"Chemistry of Materials","bibliographic_titleLang":"en"}]}]},"item_2_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Lithium-ion batteries are now successfully developed with higher energy densities than classical aqueous-based battery technologies and are used as power sources for electric vehicles and other electric storage applications. Sodium-ion batteries are another emerging battery technology, but their energy density is not high compared to that of their Li counterparts. Anionic redox reactions have attracted attention due to their potential to enhance the reversible capacity and operating voltage of positive electrode materials in Na/Li batteries. To understand the influence of Al substitution on the activation mechanism of anionic redox reactions in Na-/Li-containing Mn-based layered oxides, the P2-type Al-substituted Na2/3Al0.1Mn0.9O2 is designed to explore the difference in the anionic redox behavior. LiyAl0.1Mn0.9O2 is also prepared by electrochemical ion exchange, and the anionic redox behavior was compared for both samples. The Al-substituted Na2/3Al0.1Mn0.9O2 provides better cycling performance with partial activation of anionic redox, which is not observed for P′2-type Na2/3MnO2. Good reversibility for Na2/3Al0.1Mn0.9O2 and LiyAl0.1Mn0.9O2 with anionic redox is achieved, and this improvement originates from the nonexcessive use of anionic redox in electrode materials. This finding opens the possibility to develop high-energy sodium/lithium insertion materials with reversible anionic redox.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society","subitem_publisher_language":"en"}]},"item_2_relation_13":{"attribute_name":"item_2_relation_13","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.chemmater.4c01181","subitem_relation_type_select":"DOI"}}]},"item_2_source_id_11":{"attribute_name":"item_2_source_id_11","attribute_value_mlt":[{"subitem_source_identifier":"AA10699608","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_9":{"attribute_name":"item_2_source_id_9","attribute_value_mlt":[{"subitem_source_identifier":"08974756","subitem_source_identifier_type":"PISSN"}]},"item_2_version_type_18":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"embargoed 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Yanjia","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Department of Chemistry and Life Science, Yokohama National University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Kuriyama, Tomohiro","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"School of Materials Science and Engineering, Ocean University of China","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Jin, Yongcheng","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"0000-0002-9429-4489","nameIdentifierScheme":"ORCID","nameIdentifierURI":"https://orcid.org/0000-0002-9429-4489"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Department of Chemistry and Life Science, Yokohama National University","affiliationNameLang":"en"}]},{"affiliationNames":[{"affiliationName":"Advanced Chemical Energy Research Center, Institute of Advanced Sciences, Yokohama National University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Yabuuchi, Naoaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"0000-0002-9404-5693","nameIdentifierScheme":"ORCID","nameIdentifierURI":"https://orcid.org/0000-0002-9404-5693"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2025-09-13"}],"fileDate":[{"fileDateType":"Issued","fileDateValue":"2024-09-12"}],"filename":"CM Al-Na-Mn-O Manuscript 2nd revised v1.pdf","filesize":[{"value":"3.6 MB"}],"format":"application/pdf","url":{"objectType":"fulltext","url":"https://ynu.repo.nii.ac.jp/record/2001314/files/CM Al-Na-Mn-O Manuscript 2nd revised v1.pdf"},"version_id":"9fddcf37-191d-4d6a-b38e-9e0d70734a64"},{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2025-09-13"}],"fileDate":[{"fileDateType":"Issued","fileDateValue":"2024-09-12"}],"filename":"supporting 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Substitution on Anionic Redox Activation and Stabilization in P′2-Type Na2/3MnO2 for Na/Li Battery Applications","subitem_title_language":"en"}]},"item_type_id":"2","owner":"17","path":["496","1009"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2024-10-07"},"publish_date":"2024-10-07","publish_status":"0","recid":"2001314","relation_version_is_last":true,"title":["Influence of Aluminum Substitution on Anionic Redox Activation and Stabilization in P′2-Type Na2/3MnO2 for Na/Li Battery Applications"],"weko_creator_id":"17","weko_shared_id":-1},"updated":"2024-10-07T02:29:05.110962+00:00"}