{"created":"2023-06-20T15:14:38.927257+00:00","id":11923,"links":{},"metadata":{"_buckets":{"deposit":"75998d7c-35b4-4f4c-9c01-027c3ec24c03"},"_deposit":{"created_by":3,"id":"11923","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"11923"},"status":"published"},"_oai":{"id":"oai:ynu.repo.nii.ac.jp:00011923","sets":["495:496"]},"author_link":["34959","34963","42733"],"item_2_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-05-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"17","bibliographicPageEnd":"7871","bibliographicPageStart":"7864","bibliographicVolumeNumber":"46","bibliographic_titles":[{"bibliographic_title":"New journal of chemistry"}]}]},"item_2_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A chiral cation sensor comprising two pyrene rings and a diethylene glycol linker has been developed and utilized to detect Al3+ and Cu2+ ions based on differences in circular dichroism spectra. Remarkably, this sensor afforded the recognition of Al3+ and Cu2+ ions based on distinct differences in fluorescence spectra. The detection of Al3+ ions was achieved based on a typical excimer-to-monomer switching mechanism, whereas the oxidative dimerization of pyrenyl groups was proven to be the origin of the Cu2+-responsive switch in fluorescence spectrum. The Cu2+ cation-triggered formation of bipyrene structures, a process that has so far been overlooked in the development of pyrene-based sensors, holds promise for the generation of dual-responsive fluorescent sensors that afford the detection of two different analytes.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1039/D2NJ00801G","subitem_relation_type_select":"DOI"}}]},"item_2_relation_44":{"attribute_name":"関係URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://doi.org/10.1039/D2NJ00801G"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1039/D2NJ00801G","subitem_relation_type_select":"DOI"}}]},"item_2_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA12002155","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1369-9261","subitem_source_identifier_type":"ISSN"}]},"item_2_text_4":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry and Life Science, Graduate School of Engineering Science, Yokohama National University"},{"subitem_text_value":"Department of Chemistry and Life Science, Graduate School of Engineering Science, Yokohama National University"},{"subitem_text_value":"Department of Chemistry and Life Science, Graduate School of Engineering Science, Yokohama National University"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yuki, Matsuura"}],"nameIdentifiers":[{"nameIdentifier":"42733","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"淺見, 真年"}],"nameIdentifiers":[{"nameIdentifier":"34963","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"20134439","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=20134439"}]},{"creatorNames":[{"creatorName":"Suguru, Ito"}],"nameIdentifiers":[{"nameIdentifier":"34959","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"80724418","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=80724418"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-05-07"}],"displaytype":"detail","filename":"Accepted_Manuscript.pdf","filesize":[{"value":"8.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Accepted_Manuscript.pdf","url":"https://ynu.repo.nii.ac.jp/record/11923/files/Accepted_Manuscript.pdf"},"version_id":"871c3ed7-252f-46a9-b066-d65b1ee6fad7"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Dual-channel recognition of Al3+ and Cu2+ ions using a chiral pyrene-based fluorescent sensor","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Dual-channel recognition of Al3+ and Cu2+ ions using a chiral pyrene-based fluorescent sensor"}]},"item_type_id":"2","owner":"3","path":["496"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-05-07"},"publish_date":"2022-05-07","publish_status":"0","recid":"11923","relation_version_is_last":true,"title":["Dual-channel recognition of Al3+ and Cu2+ ions using a chiral pyrene-based fluorescent sensor"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-06-20T17:45:31.439834+00:00"}