@article{oai:ynu.repo.nii.ac.jp:00011918, author = {Shinoda, Miyuki and Hongahally, Basappa Rajendra and Yabuuchi, Naoaki}, issue = {3}, journal = {ACS Appled Energy Materials}, month = {Feb}, note = {Lithium-containing metal sulfides, LiMe0.5Ti0.5S2 (Me = Fe2+, Mn2+, and Mg2+), with cation-disordered rocksalt and a cation-ordered layered structure are synthesized and tested as electrode materials for Li battery applications. The disordered rocksalt sulfides show a better electrode performance when compared with materials with the ordered layered structure, which is a clearly different trend from lithium-containing metal oxides. Nearly all Li ions are reversibly extracted with anionic redox for rocksalt Li1–xMn0.5Ti0.5S2. Although electrode reversibility is not high because of a relatively higher solubility in carbonate-based electrolyte solution, cyclability as electrode materials is effectively improved by the use of polymer-based solid electrolyte., This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Appled Energy Materials, 2022, 5, 3. Copyright © 2022 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-WFPXZD5WPBDYVYHRYJFR.}, pages = {2642--2646}, title = {Rocksalt and Layered Metal Sulfides for Li Storage Applications: LiMe0.5Ti0.5S2 (Me = Fe2+, Mn2+, and Mg2+).}, volume = {5}, year = {2022} }