{"created":"2023-06-20T15:14:09.547476+00:00","id":11257,"links":{},"metadata":{"_buckets":{"deposit":"235de149-ad09-4e06-91d6-1439dadacc50"},"_deposit":{"created_by":3,"id":"11257","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"11257"},"status":"published"},"_oai":{"id":"oai:ynu.repo.nii.ac.jp:00011257","sets":["1006:1009"]},"author_link":["39516","39517","39518","39519","37497","35833","19251"],"control_number":"11257","item_2_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2021-02-23","bibliographicIssueDateType":"Issued"},"bibliographicNumberOfPages":"11","bibliographicPageEnd":"1831","bibliographicPageStart":"1821","bibliographicVolumeNumber":"5","bibliographic_titles":[{"bibliographic_title":"Sustainable Energy & Fuels","bibliographic_titleLang":"en"}]}]},"item_2_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The lithium–sulfur (Li–S) battery is considered one of the most promising technologies for next-generation energy storage. To realise its practical applications, electrodes with high areal sulfur loading, low-cost raw materials, and easily accessible fabrication processes are essential. Herein, we demonstrated the effectiveness of a commercially available black pigment, titanium black (TiB), as a multi-functional additive for sulfur electrodes. Benefiting from the amphipathic nature of TiB, it was easy to obtain a homogenous coating on a current collector (>4 mg cm^(−2)) by applying a traditional slurry containing aqueous carboxymethyl cellulose/styrene-butadiene rubber as a binder. Contact angle measurements revealed much better electrolyte wettability for the electrode with the addition of TiB. Combined with a sparingly solvating electrolyte based on sulfolane and Li[N(SO_2CF_3)_2], the electrode showed excellent cycling performance and high coulombic efficiency at a relatively high current density. Finally, pouch cells were fabricated with a low electrolyte/sulfur (E/S) ratio of 3.2 μL mg^(−1), and a high energy density of 280 W h kg^(−1) was achieved. Subsequent investigation of the gassing behaviour revealed that swelling of the charged cells at 60 °C was suppressed for half a month. This study may pave the way for designing Li–S batteries with practical utility.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1039/D1SE00042J","subitem_relation_type_select":"DOI"}}]},"item_2_relation_44":{"attribute_name":"関係URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://doi.org/10.1039/D1SE00042J"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1039/D1SE00042J","subitem_relation_type_select":"DOI"}}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"23984902","subitem_source_identifier_type":"EISSN"}]},"item_2_text_4":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Advanced Chemical Energy Research Centre, Institute of Advanced Sciences, Yokohama National University"},{"subitem_text_value":"Department of Chemistry and Life Science, Yokohama National University"},{"subitem_text_value":"Department of Chemistry and Life Science, Yokohama National University"},{"subitem_text_value":"Department of Chemistry and Life Science, Yokohama National University"},{"subitem_text_value":"Department of Chemistry and Life Science, Yokohama National University"},{"subitem_text_value":"Department of Chemistry and Life Science, Yokohama National University"},{"subitem_text_value":"Advanced Chemical Energy Research Centre, Institute of Advanced Sciences, Yokohama National University"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Liu, Jiali","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"39516","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Li, Shanglin","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"39517","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Marium, Mayeesha","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"39518","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Wang, Binshen","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"39519","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ueno, Kazuhide","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"37497","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"30637377","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=30637377"}]},{"creatorNames":[{"creatorName":"Dokko, Kaoru","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"35833","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70438117","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=70438117"}]},{"creatorNames":[{"creatorName":"Watanabe, Masayoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"19251","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"60158657","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=60158657"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-02-23"}],"displaytype":"detail","fileDate":[{"fileDateType":"Issued","fileDateValue":"2022-02-23"}],"filename":"Sust. Energy Fuels_TiB_R1.pdf","filesize":[{"value":"1.7 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Sust. Energy Fuels_TiB_R1.pdf","objectType":"fulltext","url":"https://ynu.repo.nii.ac.jp/record/11257/files/Sust. Energy Fuels_TiB_R1.pdf"},"version_id":"21e330a8-73ea-41f7-9a86-22c01d06bca9"},{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-02-23"}],"displaytype":"detail","filename":"Sust. Energy Fuels_TiB_SI_R1.pdf","filesize":[{"value":"2.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Sust. Energy Fuels_TiB_SI_R1.pdf","url":"https://ynu.repo.nii.ac.jp/record/11257/files/Sust. Energy Fuels_TiB_SI_R1.pdf"},"version_id":"dc1ce785-6721-4fa7-968f-dc7e5ca8f61c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Towards practical cells: combined use of titanium black as a cathode additive and sparingly solvating electrolyte for high-energy-density lithium–sulfur batteries","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Towards practical cells: combined use of titanium black as a cathode additive and sparingly solvating electrolyte for high-energy-density lithium–sulfur batteries","subitem_title_language":"en"}]},"item_type_id":"2","owner":"3","path":["1009"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2021-06-04"},"publish_date":"2021-06-04","publish_status":"0","recid":"11257","relation_version_is_last":true,"title":["Towards practical cells: combined use of titanium black as a cathode additive and sparingly solvating electrolyte for high-energy-density lithium–sulfur batteries"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2024-04-26T04:05:12.791382+00:00"}