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Direct comparison of the flame inhibition efficiency of transition metals using metallocenes
http://hdl.handle.net/10131/00012071
http://hdl.handle.net/10131/000120716190460b-5994-4e31-9e47-7ee8186a34b9
名前 / ファイル | ライセンス | アクション |
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Fire Saf J 73 (2015) 48-54.pdf (639.0 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-11-08 | |||||
タイトル | ||||||
タイトル | Direct comparison of the flame inhibition efficiency of transition metals using metallocenes | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | Flame inhibition, Metallocene, Transition metal, Flame spread rate, Kissinger method | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Koshiba, Yusuke
× Koshiba, Yusuke× Agata, Saori× Takahashi, Tomohide× Ohtani, Hideo |
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著者所属 | ||||||
Department of Materials Science and Chemical Engineering, Faculty of Engineering, Yokohama National University | ||||||
著者所属 | ||||||
College of Engineering, Yokohama National University | ||||||
著者所属 | ||||||
College of Engineering, Yokohama National University | ||||||
著者所属 | ||||||
Department of Safety Management, Faculty of Environmental and Information Sciences, Yokohama National University | ||||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | This study aimed to directly and systematically compare the flame inhibition abilities of various transition metals, including vanadium, ruthenium, osmium, chromium, manganese, iron, cobalt, and nickel, by using the corresponding metallocenes: vanadocene, ruthenocene, osmocene, chromocene, manganocene, ferrocene, cobaltocene, and nickelocene. The downward flame spread rates over filter paper samples on which each metallocene was adsorbed were measured. In addition, thermogravimetric measurements were carried out to finally determine the phase in which each metallocene produced its flame inhibition effect. The results indicated that all these metallocenes, with the exception of vanadocene, exhibit a flame inhibition effect solely in the gas phase, whereas vanadocene shows fire suppression ability in the solid phase. This work also found that, in terms of their fire suppression abilities, the transition metals can be ranked in the following order: Cr>Mn>Fe>Co>Ni>(V>)Os>Ru. | |||||
書誌情報 |
Fire Safety Journal 巻 73, p. 48-54, 発行日 2015-04 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 03797112 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1016/j.firesaf.2015.03.003 | |||||
権利 | ||||||
権利情報 | © 2015, Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
出版者 | ||||||
出版者 | Elsevier B.V. |