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Optical Properties of Three Differently Colored Crystal Modifications of a 2,3-Dicyanopyrazine Dye
http://hdl.handle.net/10131/00011983
http://hdl.handle.net/10131/00011983976e278c-7c1f-4bbd-9a1c-9c3c4f083f34
名前 / ファイル | ライセンス | アクション |
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bcsj.20140409.pdf (815.1 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-09-11 | |||||
タイトル | ||||||
タイトル | Optical Properties of Three Differently Colored Crystal Modifications of a 2,3-Dicyanopyrazine Dye | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Okada, Naoya
× Okada, Naoya× Eto, Ryohei× Babamoto-Horiguchi, Emi× Kobayashi, Takashi× Naito, Hiroyoshi× Shiro, Motoo× Takahashi, Hiromi× Matsumoto, Shinya |
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著者所属 | ||||||
Department of Environment and Natural Sciences, Graduate School of Environment and Information Sciences, Yokohama National University | ||||||
著者所属 | ||||||
Department of Environment and Natural Sciences, Graduate School of Environment and Information Sciences, Yokohama National University | ||||||
著者所属 | ||||||
Department of Pharmaceutical Sciences, Faculty of Pharmaceutics, Musashino University | ||||||
著者所属 | ||||||
Department of Physics and Electronics, Graduate School of Engineering, Osaka Prefecture University | ||||||
著者所属 | ||||||
Department of Physics and Electronics, Graduate School of Engineering, Osaka Prefecture University | ||||||
著者所属 | ||||||
X-ray Research Laboratory, Rigaku Corporation | ||||||
著者所属 | ||||||
System Instruments Co., Ltd. | ||||||
著者所属 | ||||||
Department of Environment and Natural Sciences, Graduate School of Environment and Information Sciences, Yokohama National University | ||||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Optical properties of three crystal modifications of 5-t-butyl-2,3-dicyano-6-[4-(dimethylamino)styryl]pyrazine having different color appearances were measured and interpreted on the basis of crystal structure analysis. Two of the three modifications exhibited a bathochromic spectral shift both in absorption and fluorescence compared with those in a toluene solution of the dye. The crystal structure analysis revealed that a two-dimensional brick-wall structure is formed in both modifications. In contrast, the third modification showed a hypsochromic absorption shift with a large bathochromic fluorescence shift. The crystal structure of this modification was characterized by a one-dimensional stacked molecular column. The optical characteristics of the three modifications were qualitatively interpreted in terms of excitonic intermolecular interaction on the basis of their crystal structures. | |||||
書誌情報 |
Bulletin of the Chemical Society of Japan 巻 88, 号 5, p. 716-721, 発行日 2015 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00092673 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00580132 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1246/bcsj.20140409 | |||||
権利 | ||||||
権利情報 | © 2015 The Chemical Society of Japan | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
出版者 | ||||||
出版者 | Chemical Society of Japan |