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Photoinduced debenzylation of 2,5-bis(dibenzylamino)-3,6-dichloro-p-benzoquinone
http://hdl.handle.net/10131/00011979
http://hdl.handle.net/10131/00011979569183d0-baa2-41d2-a0c2-97c654789929
名前 / ファイル | ライセンス | アクション |
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revised_manuscript_170512.pdf (230.0 kB)
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Figure and Table.pdf (502.4 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-09-10 | |||||
タイトル | ||||||
タイトル | Photoinduced debenzylation of 2,5-bis(dibenzylamino)-3,6-dichloro-p-benzoquinone | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | Aminobenzoquinone, Photoreaction, Benzyl group, Photoelimination, Sunlight, Radical reaction | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Shin, In-Sub
× Shin, In-Sub× Shimada, Yuta× Ishihara, Shinji× Horiguchi-Babamoto, Emi× Matsumoto, Shinya |
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著者所属 | ||||||
Graduate School of Environment and Information Sciences, Yokohama National University | ||||||
著者所属 | ||||||
Graduate School of Environment and Information Sciences, Yokohama National University | ||||||
著者所属 | ||||||
Instrumental Analysis Center, Yokohama National University | ||||||
著者所属 | ||||||
Department of Pharmaceutical Sciences, Faculty of Pharmacy, Musashino University | ||||||
著者所属 | ||||||
Graduate School of Environment and Information Sciences, Yokohama National University | ||||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | In this detailed study of the photoreaction of 2,5-bis(dibenzylamino)-3,6-dichloro-p-benzoquinone, two new products were separated along with the previously reported debenzylated analogues, and their molecular structure was determined. One compound was identified as 2-(benzylamino)-3,6-dichloro-5-(dibenzylamino)-p-benzoquinone, which was found to undergo further debenzylation to form the two known debenzylated analogues. The other compound was identified as the hydroquinone form of the starting material. This photoreaction was examined in detail using various analytical techniques under different experimental conditions, and a plausible reaction pathway was proposed on the basis of the experimental results. In addition, the reaction was found to occur also under sunlight irradiation. | |||||
書誌情報 |
Dyes and Pigments 巻 144, p. 110-118, 発行日 2017-09 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 01437208 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11525555 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1016/j.dyepig.2017.05.028 | |||||
権利 | ||||||
権利情報 | © 2017 Elsevier Ltd. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
出版者 | ||||||
出版者 | Elsevier Science |