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J-aggregate structure in a chloroform solvate of a 2,3-dicyanopyrazine dye – Separation of two-dimensional stacking dye layers by solvate formation
http://hdl.handle.net/10131/00010802
http://hdl.handle.net/10131/00010802197d98b2-b2e8-4767-8bf4-30085161212a
名前 / ファイル | ライセンス | アクション |
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matsumoto_16.pdf (127.7 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-05-01 | |||||
タイトル | ||||||
タイトル | J-aggregate structure in a chloroform solvate of a 2,3-dicyanopyrazine dye – Separation of two-dimensional stacking dye layers by solvate formation | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Matsumoto, Shinya
× Matsumoto, Shinya× Horiguchi-Babamoto, Emi× Eto, Ryohei× Sato, Saori× Kobayashi, Takashi× Naito, Hiroyoshi× Shiro, Motoo× Takahashi, Hiromi |
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著者所属 | ||||||
Department of Environmental Sciences, Graduate School of Environment and Information Sciences, Yokohama National University | ||||||
著者所属 | ||||||
Department of Pharmaceutical Sciences, Faculty of Pharmaceutics, Musashino University | ||||||
著者所属 | ||||||
Department of Environmental Sciences, Graduate School of Environment and Information Sciences, Yokohama National University | ||||||
著者所属 | ||||||
Department of Environmental Sciences, Graduate School of Environment and Information Sciences, Yokohama National University | ||||||
著者所属 | ||||||
Department of Physics and Electronics, Graduate School of Engineering, Osaka Prefecture University | ||||||
著者所属 | ||||||
Department of Physics and Electronics, Graduate School of Engineering, Osaka Prefecture University | ||||||
著者所属 | ||||||
X-ray Research Laboratory, Rigaku Corporation | ||||||
著者所属 | ||||||
System Instruments Co., Ltd. | ||||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Here, we report the J-aggregate structure of a chloroform solvate of 5-t-butyl-2,3-dicyano-6-[4-(dimethylamino)styryl]-pyrazine with a strong intramolecular charge transfer system. The dye was found to form a two-dimensional brick-wall structure separated by chloroform molecules in the solvated crystals, which exhibited intense red fluorescence. The absorption maximum of the solvate was also found to show a bathochromic spectral shift. These observed optical characteristics were interpreted in terms of excitonic intermolecular interaction based on two-dimensional brick-wall structure which is one of the proposed structures for J-aggregates. | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | ©2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | |||||
書誌情報 |
Dyes and Pigments 巻 95, 号 2, p. 431-435, 発行日 2012-11 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 01437208 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11525555 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.dyepig.2012.04.014 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
出版者 | ||||||
出版者 | Elsevier Science |