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Rocksalt and Layered Metal Sulfides for Li Storage Applications: LiMe0.5Ti0.5S2 (Me = Fe2+, Mn2+, and Mg2+).
http://hdl.handle.net/10131/00014574
http://hdl.handle.net/10131/00014574d3975c51-7278-4849-86fc-9918338540b7
名前 / ファイル | ライセンス | アクション |
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ACS Mater Lett LMTS Manuscript Formatted Revised v1 without highlight.pdf (728.4 kB)
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ACS Mater Lett LMTS supporting information revised v1 without highlight.pdf (1.9 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2022-05-09 | |||||
タイトル | ||||||
タイトル | Rocksalt and Layered Metal Sulfides for Li Storage Applications: LiMe0.5Ti0.5S2 (Me = Fe2+, Mn2+, and Mg2+). | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | metal sulfide, anionic redox, rocksalt sulfides, lithium battery, polymer battery | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Shinoda, Miyuki
× Shinoda, Miyuki× Hongahally, Basappa Rajendra× Yabuuchi, Naoaki |
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著者所属 | ||||||
Department of Chemistry and Life Science, Yokohama National University | ||||||
著者所属 | ||||||
Advanced Chemical Energy Research Center, Institute of Advanced Sciences, Yokohama National University | ||||||
著者所属 | ||||||
Department of Chemistry and Life Science, Yokohama National University & Advanced Chemical Energy Research Center, Institute of Advanced Sciences, Yokohama National University & Elements Strategy Initiative for Catalysts and Batteries, Kyoto University | ||||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Lithium-containing metal sulfides, LiMe0.5Ti0.5S2 (Me = Fe2+, Mn2+, and Mg2+), with cation-disordered rocksalt and a cation-ordered layered structure are synthesized and tested as electrode materials for Li battery applications. The disordered rocksalt sulfides show a better electrode performance when compared with materials with the ordered layered structure, which is a clearly different trend from lithium-containing metal oxides. Nearly all Li ions are reversibly extracted with anionic redox for rocksalt Li1–xMn0.5Ti0.5S2. Although electrode reversibility is not high because of a relatively higher solubility in carbonate-based electrolyte solution, cyclability as electrode materials is effectively improved by the use of polymer-based solid electrolyte. | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Appled Energy Materials, 2022, 5, 3. Copyright © 2022 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/articlesonrequest/AOR-WFPXZD5WPBDYVYHRYJFR. | |||||
書誌情報 |
ACS Appled Energy Materials 巻 5, 号 3, p. 2642-2646, 発行日 2022-02-24 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 2574-0962 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1021/acsaem.1c04044 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
出版者 | ||||||
出版者 | American Chemical Society | |||||
関係URI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1021/acsaem.1c04044 | |||||
関連名称 | https://doi.org/10.1021/acsaem.1c04044 |