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Nanosized and metastable molybdenum oxides as negative electrode materials for durable high-energy aqueous Li-ion batteries
http://hdl.handle.net/10131/00014118
http://hdl.handle.net/10131/000141188ee087ab-b354-42b0-9fa8-af83c404012b
名前 / ファイル | ライセンス | アクション |
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e2024969118.full.pdf (1.6 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2021-12-13 | |||||
タイトル | ||||||
タイトル | Nanosized and metastable molybdenum oxides as negative electrode materials for durable high-energy aqueous Li-ion batteries | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | aqueous battery, metastable, rock-salt oxide | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Jeongsik, Yun
× Jeongsik, Yun× Ryota, Sagehashi× Yoshihiko, Sato× Takuya, Masuda× Satoshi, Hoshino× Hongahally, Basappa Rajendra× Kazuki, Okuno× Akihisa, Hosoe× Aliaksandr, S. Bandarenka× Naoaki, Yabuuchi |
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著者所属 | ||||||
Physics of Energy Conversion and Storage, Physik-Department, Technische Universität München | ||||||
著者所属 | ||||||
Department of Applied Chemistry, Tokyo Denki University | ||||||
著者所属 | ||||||
Department of Chemistry and Life Science, Yokohama National University | ||||||
著者所属 | ||||||
Research Center for Advanced Measurement and Characterization, National Institute for Materials Science | ||||||
著者所属 | ||||||
Department of Applied Chemistry, Tokyo Denki University | ||||||
著者所属 | ||||||
Department of Chemistry and Life Science, Yokohama National University | ||||||
著者所属 | ||||||
Energy and Electronics Materials R&D Laboratories, Sumitomo Electric Industries, Ltd. | ||||||
著者所属 | ||||||
Energy and Electronics Materials R&D Laboratories, Sumitomo Electric Industries, Ltd. | ||||||
著者所属 | ||||||
Physics of Energy Conversion and Storage, Physik-Department, Technische Universität München | ||||||
著者所属 | ||||||
Department of Chemistry and Life Science, Yokohama National University & Advanced Chemical Energy Research Center, Yokohama National University & Elements Strategy Initiative for Catalysts and Batteries, Kyoto University | ||||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | This study describes a high-energy and durable aqueous battery system with metastable and nanosized Mo-based oxides used as high-capacity negative electrodes. A wider electrochemical window is achieved with concentrated aqueous electrolytes through which highly reversible Li storage without the decomposition of water molecules is achieved for the Mo-based oxides. A full cell with an Mn-based oxide shows good capacity retention over 2,000 cycles. X-ray absorption spectroscopy reveals that the solid-state redox reaction of Mo ions reversibly proceeds in aqueous electrolytes for the metastable Mo oxide. This study opens a way to develop high-energy, durable, and safe batteries on the basis of metastable and nanosized oxides with aqueous electrolyte solutions. | |||||
書誌情報 |
Proceedings of the National Academy of Sciences of the United States of America 巻 118, 号 48, p. e2024969118, 発行日 2021-10-22 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1091-6490 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12104563 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1073/pnas.2024969118 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | National Academy of Sciences | |||||
関係URI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1073/pnas.2024969118 | |||||
関連名称 | https://doi.org/10.1073/pnas.2024969118 |