WEKO3
アイテム
{"_buckets": {"deposit": "fb9beeac-86e0-4b5c-80a6-7625a4279458"}, "_deposit": {"created_by": 3, "id": "11382", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "11382"}, "status": "published"}, "_oai": {"id": "oai:ynu.repo.nii.ac.jp:00011382", "sets": ["496"]}, "author_link": ["19251", "37497", "35833", "40177", "40179", "40178"], "item_2_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2021-09-15", "bibliographicIssueDateType": "Issued"}, "bibliographic_titles": [{"bibliographic_title": "Physical chemistry, chemical physics"}]}]}, "item_2_description_5": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Polar solvents dissolve Li and Na salts at high concentrations and are used as electrolyte solutions for batteries. The solvents interact strongly with the alkali metal cations to form complexes in the solution. The activity (concentration) of the uncoordinated solvent decreases as the salt concentration is increased. At extremely high salt concentrations, all the solvent molecules are involved in the coordination of the ions and form the solvates of the salts. In this article, we review the structures, transport properties, and electrochemistry of Li/Na salt solvates. In molten solvates, the activity of the uncoordinated solvent is negligible; this is the main origin of their peculiar characteristics, such as high thermal stability, wide electrochemical window, and unique ion transport. In addition, the solvent activity greatly influences the electrochemical reactions in Li/Na batteries. We highlight the attractive features of molten solvates as promising electrolytes for next-generation batteries.", "subitem_description_type": "Abstract"}]}, "item_2_publisher_35": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Royal Society of Chemistry"}]}, "item_2_relation_13": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "info:doi/10.1039/D1CP02946K", "subitem_relation_type_select": "DOI"}}]}, "item_2_relation_44": {"attribute_name": "関係URI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "https://doi.org/10.1039/D1CP02946K"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1039/D1CP02946K", "subitem_relation_type_select": "DOI"}}]}, "item_2_source_id_11": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA11723355", "subitem_source_identifier_type": "NCID"}]}, "item_2_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "14639076", "subitem_source_identifier_type": "ISSN"}]}, "item_2_text_4": {"attribute_name": "著者所属", "attribute_value_mlt": [{"subitem_text_value": "Department of Chemistry and Life Science, Yokohama National University"}, {"subitem_text_value": "Department of Chemistry and Life Science, Yokohama National University"}, {"subitem_text_value": "Department of Applied Chemistry, Tokyo University of Science \u0026 Unit of Elements Strategy Initiative for Catalysts \u0026 Batteries (ESICB), Kyoto University"}, {"subitem_text_value": "Department of Chemistry and Life Science, Yokohama National University \u0026 Advanced Chemical Energy Research Center, Institute of Advanced Sciences, Yokohama National University "}, {"subitem_text_value": " Department of Applied Chemistry, Tokyo University of Science "}, {"subitem_text_value": "Department of Chemistry and Life Science, Yokohama National University \u0026 Unit of Elements Strategy Initiative for Catalysts \u0026 Batteries (ESICB), Kyoto University \u0026 Advanced Chemical Energy Research Center, Institute of Advanced Sciences, Yokohama National University"}]}, "item_2_version_type_18": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yosuke, Ugata"}], "nameIdentifiers": [{"nameIdentifier": "40177", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Keisuke, Shigenobu"}], "nameIdentifiers": [{"nameIdentifier": "40178", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ryoichi, Tatara"}], "nameIdentifiers": [{"nameIdentifier": "40179", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "20876081", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=20876081"}]}, {"creatorNames": [{"creatorName": "Kazuhide, Ueno"}], "nameIdentifiers": [{"nameIdentifier": "37497", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "30637377", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=30637377"}]}, {"creatorNames": [{"creatorName": "Masayoshi, Watanabe"}], "nameIdentifiers": [{"nameIdentifier": "19251", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "60158657", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=60158657"}]}, {"creatorNames": [{"creatorName": "Kaoru, Dokko"}], "nameIdentifiers": [{"nameIdentifier": "35833", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "70438117", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=70438117"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2021-09-30"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "d1cp02946k.pdf", "filesize": [{"value": "10.6 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 10600000.0, "url": {"label": "d1cp02946k.pdf", "url": "https://ynu.repo.nii.ac.jp/record/11382/files/d1cp02946k.pdf"}, "version_id": "ccdc4b79-96cf-4dc7-8411-d5b8f8f76721"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Solvate electrolytes for Li and Na batteries: structures, transport properties, and electrochemistry", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Solvate electrolytes for Li and Na batteries: structures, transport properties, and electrochemistry"}]}, "item_type_id": "2", "owner": "3", "path": ["496"], "permalink_uri": "http://hdl.handle.net/10131/00014041", "pubdate": {"attribute_name": "公開日", "attribute_value": "2021-09-30"}, "publish_date": "2021-09-30", "publish_status": "0", "recid": "11382", "relation": {}, "relation_version_is_last": true, "title": ["Solvate electrolytes for Li and Na batteries: structures, transport properties, and electrochemistry"], "weko_shared_id": -1}
Solvate electrolytes for Li and Na batteries: structures, transport properties, and electrochemistry
http://hdl.handle.net/10131/00014041
http://hdl.handle.net/10131/00014041c31cff1e-f1b6-4e66-9914-59dd02d444ae
名前 / ファイル | ライセンス | アクション |
---|---|---|
d1cp02946k.pdf (10.6 MB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2021-09-30 | |||||
タイトル | ||||||
タイトル | Solvate electrolytes for Li and Na batteries: structures, transport properties, and electrochemistry | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Yosuke, Ugata
× Yosuke, Ugata× Keisuke, Shigenobu× Ryoichi, Tatara× Kazuhide, Ueno× Masayoshi, Watanabe× Kaoru, Dokko |
|||||
著者所属 | ||||||
Department of Chemistry and Life Science, Yokohama National University | ||||||
著者所属 | ||||||
Department of Chemistry and Life Science, Yokohama National University | ||||||
著者所属 | ||||||
Department of Applied Chemistry, Tokyo University of Science & Unit of Elements Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University | ||||||
著者所属 | ||||||
Department of Chemistry and Life Science, Yokohama National University & Advanced Chemical Energy Research Center, Institute of Advanced Sciences, Yokohama National University | ||||||
著者所属 | ||||||
Department of Applied Chemistry, Tokyo University of Science | ||||||
著者所属 | ||||||
Department of Chemistry and Life Science, Yokohama National University & Unit of Elements Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University & Advanced Chemical Energy Research Center, Institute of Advanced Sciences, Yokohama National University | ||||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Polar solvents dissolve Li and Na salts at high concentrations and are used as electrolyte solutions for batteries. The solvents interact strongly with the alkali metal cations to form complexes in the solution. The activity (concentration) of the uncoordinated solvent decreases as the salt concentration is increased. At extremely high salt concentrations, all the solvent molecules are involved in the coordination of the ions and form the solvates of the salts. In this article, we review the structures, transport properties, and electrochemistry of Li/Na salt solvates. In molten solvates, the activity of the uncoordinated solvent is negligible; this is the main origin of their peculiar characteristics, such as high thermal stability, wide electrochemical window, and unique ion transport. In addition, the solvent activity greatly influences the electrochemical reactions in Li/Na batteries. We highlight the attractive features of molten solvates as promising electrolytes for next-generation batteries. | |||||
書誌情報 |
Physical chemistry, chemical physics 発行日 2021-09-15 |
|||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 14639076 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11723355 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1039/D1CP02946K | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
出版者 | ||||||
出版者 | Royal Society of Chemistry | |||||
関係URI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1039/D1CP02946K | |||||
関連名称 | https://doi.org/10.1039/D1CP02946K |