| 著者 |
Asano, Erika
| en |
Asano, Erika
Grad Sch Engn, Dept Adv Mat Chem, Hodogaya Ku, Yokohama National University
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Hatayama, Yuki
| en |
Hatayama, Yuki
Grad Sch Engn, Dept Adv Mat Chem, Hodogaya Ku, Yokohama National University
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Kurisu, Nobutaka
| en |
Kurisu, Nobutaka
Grad Sch Engn, Dept Adv Mat Chem, Hodogaya Ku, Yokohama National University
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Ohtani, Atsufumi
| en |
Ohtani, Atsufumi
Grad Sch Engn, Dept Adv Mat Chem, Hodogaya Ku, Yokohama National University
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Hashimoto, Toru
Kurihara, Youji
| en |
Kurihara, Youji
Grad Sch Engn, Dept Adv Mat Chem, Hodogaya Ku, Yokohama National University
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Ueda, Kazuyoshi
Ishihara, Shinji
Nagao, Hirotaka
ORCID
0000-0001-9630-7602
| en |
Nagao, Hirotaka
Grad Sch Engn, Dept Adv Mat Chem, Hodogaya Ku, Instrumental Anal Ctr, Hodogaya Ku, Fac Sci & Technol, Dept Mat & Life Sci, Chiyoda Ku, Sophia University
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Yamaguchi, Yoshitaka
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内容記述 |
In this work, three different types of acetylacetonato-based pincer-type nickel(ii) complexes (2) were prepared. Complex 2a possessed the tridentate ONN ligand, which was constructed by the condensation reaction of acetylacetone with N,N-diethylethylenediamine. Complex 2b contained the PPh2 donor group in contrast to the NEt2 group in 2a, i.e., an ONP ligand framework. Complex 2c was composed of the NNN ligand, which was prepared by the reaction of 4-((2,4,6-trimethylphenyl)amino)pent-3-en-2-one with N,N-diethylethylenediamine. In addition to X-ray diffraction analysis, these complexes were characterized spectroscopically. Their catalytic activity for a cross-coupling reaction of aryl halides with aryl Grignard reagents was also evaluated. Among these complexes, 2b acted as an effective catalyst for the cross-coupling reaction using aryl chlorides as electrophiles. The electronic properties of these Ni(ii) complexes were investigated by cyclic voltammetry and density functional theory calculations. |
DT2018_47_8003.pdf (889.8 kB)
