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A β‐Diketiminato‐Based Pincer‐Type Nickel(II) Complex: Synthesis and Catalytic Performance in the Cross‐Coupling of Aryl Fluorides with Aryl Grignard Reagents
http://hdl.handle.net/10131/00012724
http://hdl.handle.net/10131/00012724d9c6b8a6-5674-474d-8d45-145d339fa258
名前 / ファイル | ライセンス | アクション |
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_ejic201801179.pdf (1.3 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2019-08-28 | |||||
タイトル | ||||||
タイトル | A β‐Diketiminato‐Based Pincer‐Type Nickel(II) Complex: Synthesis and Catalytic Performance in the Cross‐Coupling of Aryl Fluorides with Aryl Grignard Reagents | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | Nickel, Pincer ligands, β‐Diketiminato frameworks, Aryl fluorides, Cross‐coupling, Homogeneous catalysis | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Kurisu, Nobutaka
× Kurisu, Nobutaka× Asano, Erika× Hatayama, Yuki× Kurihara, Youji× Hashimoto, Toru× Funatsu, Kei× Ueda, Kazuyoshi× Yamaguchi, Yoshitaka |
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著者所属 | ||||||
Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University | ||||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A β‐diketiminato‐based tridentate pincer‐type nickel(II) complex Ni‐NNP was prepared by the reaction of the nickel(II) precursor [NiCl2(2,4‐lutidine)2] with the lithiated NNP ligand, which was generated in situ by the reaction of the NNP pro‐ligand H‐NNP with nBuLi. H‐NNP was prepared by the condensation of 4‐[(2,4,6‐trimethylphenyl)amino]pent‐3‐en‐2‐one with 2‐(diphenylphosphanyl)ethylamine. Ni‐NNP was characterized spectroscopically and by X‐ray diffraction, revealing a slightly distorted square‐planar geometry around the nickel center. Density functional theory calculations indicated that the highest occupied molecular orbital in Ni‐NNP is located at higher energy than those of three other homologous nickel(II) complexes, i.e., Ni‐ONN, Ni‐ONP, and Ni‐NNN, which contain β‐aminoketonato‐ or β‐diketiminato‐based pincer‐type ligands. The electronic and steric properties of Ni‐NNP effectively facilitated the cross‐coupling of aryl fluorides with aryl Grignard reagents. | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | This is the peer reviewed version of the following article: [Nobutaka Kurisu et al, 2019, The European Journal of Inorganic Chemistry, 2019 1 126-133], which has been published in final form at [https://doi.org/10.1002/ejic.201801179]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | |||||
書誌情報 |
The European Journal of Inorganic Chemistry 巻 2019, 号 1, p. 126-133, 発行日 2019-01-10 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 10990682 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11619819 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1002/ejic.201801179 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
出版者 | ||||||
出版者 | Wiley |