| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2019-08-28 |
| タイトル |
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タイトル |
A β-Diketiminato-Based Pincer-Type Nickel(II) Complex: Synthesis and Catalytic Performance in the Cross-Coupling of Aryl Fluorides with Aryl Grignard Reagents |
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言語 |
en |
| 言語 |
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|
言語 |
eng |
| キーワード |
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言語 |
en |
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主題Scheme |
Other |
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主題 |
Nickel; Pincer ligands; beta-Diketiminato frameworks; Aryl fluorides; Cross-coupling; Homogeneous catalysis |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| アクセス権 |
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|
アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 著者 |
Kurisu, Nobutaka
| en |
Kurisu, Nobutaka
Grad Sch Engn, Dept Adv Mat Chem, Hodogaya Ku, Yokohama National University
|
Search repository
Asano, Erika
| en |
Asano, Erika
Grad Sch Engn, Dept Adv Mat Chem, Hodogaya Ku, Yokohama National University
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Search repository
Hatayama, Yuki
| en |
Hatayama, Yuki
Grad Sch Engn, Dept Adv Mat Chem, Hodogaya Ku, Yokohama National University
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Search repository
Kurihara, Youji
| en |
Kurihara, Youji
Grad Sch Engn, Dept Adv Mat Chem, Hodogaya Ku, Yokohama National University
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Search repository
Hashimoto, Toru
Funatsu, Kei
| en |
Funatsu, Kei
Grad Sch Engn, Dept Adv Mat Chem, Hodogaya Ku, Yokohama National University
|
Search repository
Ueda, Kazuyoshi
Yamaguchi, Yoshitaka
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| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
A beta-diketiminato-based tridentate pincer-type nickel(II) complex Ni-NNP was prepared by the reaction of the nickel(II) precursor [NiCl2(2,4-lutidine)(2)] with the lithiated NNP ligand, which was generated in situ by the reaction of the NNP pro-ligand H-NNP with nBuLi. H-NNP was prepared by the condensation of 4-[(2,4,6-trimethylphenyl)amino]pent-3-en-2-one with 2-(diphenylphosphanyl)ethylamine. Ni-NNP was characterized spectroscopically and by X-ray diffraction, revealing a slightly distorted square-planar geometry around the nickel center. Density functional theory calculations indicated that the highest occupied molecular orbital in Ni-NNP is located at higher energy than those of three other homologous nickel(II) complexes, i.e., Ni-ONN, Ni-ONP, and Ni-NNN, which contain beta-aminoketonato- or beta-diketiminato-based pincer-type ligands. The electronic and steric properties of Ni-NNP effectively facilitated the cross-coupling of aryl fluorides with aryl Grignard reagents. |
|
言語 |
en |
| 書誌情報 |
en : European Journal of Inorganic Chemistry
号 1,
p. 126-133,
ページ数 8,
発行日 2019-01-10
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| ISSN |
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収録物識別子タイプ |
PISSN |
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収録物識別子 |
14341948 |
| DOI |
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関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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関連識別子 |
https://doi.org/10.1002/ejic.201801179 |
| 権利 |
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言語 |
en |
|
権利情報Resource |
https://authorservices.wiley.com/author-resources/Journal-Authors/licensing/self-archiving.html |
|
権利情報 |
This is the peer reviewed version of the following article: A β‐Diketiminato‐Based Pincer‐Type Nickel(II) Complex: Synthesis and Catalytic Performance in the Cross‐Coupling of Aryl Fluorides with Aryl Grignard Reagents, which has been published in final form at https://doi.org/10.1002/ejic.201801179 . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. |
| 著者版フラグ |
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出版タイプ |
AM |
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出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 出版者 |
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出版者 |
Wiley-V C H Verlag GmbH |
|
言語 |
en |
_ejic201801179.pdf (1.3 MB)
