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Oil-in-water microemulsion containing ferrocene: A new fire suppressant
http://hdl.handle.net/10131/00012069
http://hdl.handle.net/10131/00012069135325a3-68b9-493b-a73b-820408e3c883
名前 / ファイル | ライセンス | アクション |
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Fire Saf. J. 98 (2018) 82-89.pdf (1.7 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-11-08 | |||||
タイトル | ||||||
タイトル | Oil-in-water microemulsion containing ferrocene: A new fire suppressant | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | Fire suppression, Ferrocene, Oil-in-water microemulsion, Phosphorus free, Fire-extinguishing agent, Water mist, Noigen TDS-80 (Lutensol TO 89), Surfactant, Extinguishment, Pool fire | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Koshiba, Yusuke
× Koshiba, Yusuke× Tomita, Takuya× Ohtani, Hideo |
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著者所属 | ||||||
Department of Materials Science and Chemical Engineering, Faculty of Engineering, Yokohama National University | ||||||
著者所属 | ||||||
Graduate School of Environmental and Information Sciences, Yokohama National University | ||||||
著者所属 | ||||||
Department of Safety Management, Faculty of Environmental and Information Sciences, Yokohama National University | ||||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | This paper reports the preparation and fire-suppression efficiency of oil-in-water microemulsions containing ferrocene. In this work, oil-in-water emulsions containing 0–1000 ppm ferrocene and four surfactants (Surfynol 465, Olfin E1020, Triton X-100 (TX), and Noigen TDS-80 (NT)) were prepared by homogenizing n-octane solutions of ferrocene and aqueous surfactant solutions at ambient temperature. Four emulsion parameters were then characterized: emulsion stability, oil-droplet size in emulsion, flash point, and capability of extinguishing n-heptane pool fires. Emulsion stability experiments and droplet-size measurements clearly demonstrated that the oil-in-water emulsions containing ferrocene and TX/NT were thermodynamically stable microemulsions. Flash-point measurements confirmed that no oil-in-water microemulsions tested ignited below 93 °C. Suppression trials involving microemulsions containing 0–1000 ppm ferrocene and NT revealed the relationship between their fire suppression efficiency and the concentrations of ferrocene and NT, and also demonstrated that the microemulsions tested in this study have a higher ability to suppress pool fires compared with a conventional wet chemical agent. | |||||
書誌情報 |
Fire Safety Journal 巻 98, p. 82-89, 発行日 2018-06 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 03797112 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1016/j.firesaf.2018.04.005 | |||||
権利 | ||||||
権利情報 | © 2018, Elsevier B.V. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
出版者 | ||||||
出版者 | Elsevier B.V. |