WEKO3
アイテム
{"_buckets": {"deposit": "e3a71c06-5f90-437c-8e78-90f877245d77"}, "_deposit": {"created_by": 3, "id": "11258", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "11258"}, "status": "published"}, "_oai": {"id": "oai:ynu.repo.nii.ac.jp:00011258", "sets": ["1009"]}, "author_link": ["36084", "19251", "37497", "39522", "39521", "39520"], "item_2_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2021-05-24", "bibliographicIssueDateType": "Issued"}, "bibliographicPageStart": "2100091", "bibliographicVolumeNumber": "42", "bibliographic_titles": [{"bibliographic_title": "Macromolecular rapid communications"}]}]}, "item_2_description_5": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Using atomic force microscopy, the photo-induced reversible changes in a block copolymer self-assembly containing an azobenzene ionic liquid, which undergoes sol–gel transition is directly observed. This is the first report on the sol–gel transition of an ABA-type block copolymer consisting of upper critical solution temperature (UCST)-type A blocks in a photoresponsive ionic liquid mixture. The sol–gel transition is accompanied by an order-to-disorder structural change, which subsequently induces a change in the ionic conductivity. Surprisingly, the photo-induced ionic conductivity and rheological changes occurs rapidly (≈30 s) despite the dense (≈80 wt%) polymeric system. The rapid structural change is probably attributable to the fast diffusion of the ionic liquid.", "subitem_description_type": "Abstract"}]}, "item_2_publisher_35": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_2_relation_13": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "info:doi/10.1002/marc.202100091", "subitem_relation_type_select": "DOI"}}]}, "item_2_relation_44": {"attribute_name": "関係URI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "https://doi.org/10.1002/marc.202100091"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/marc.202100091", "subitem_relation_type_select": "DOI"}}]}, "item_2_source_id_11": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA11625232", "subitem_source_identifier_type": "NCID"}]}, "item_2_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "15213927", "subitem_source_identifier_type": "ISSN"}]}, "item_2_text_4": {"attribute_name": "著者所属", "attribute_value_mlt": [{"subitem_text_value": "Department of Chemistry and Life Science Yokohama National University"}, {"subitem_text_value": "Institute of Advanced Sciences Yokohama National University"}, {"subitem_text_value": "Department of Chemistry and Life Science Yokohama National University"}, {"subitem_text_value": "Department of Chemistry and Life Science Yokohama National University"}, {"subitem_text_value": "Department of Chemistry and Life Science Yokohama National University"}, {"subitem_text_value": "Institute of Advanced Sciences Yokohama National University"}]}, "item_2_version_type_18": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Mizuno, Haruna"}], "nameIdentifiers": [{"nameIdentifier": "39520", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hashimoto, Kei"}], "nameIdentifiers": [{"nameIdentifier": "39521", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "20888276", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=20888276"}]}, {"creatorNames": [{"creatorName": "Shigenobu, Keisuke"}], "nameIdentifiers": [{"nameIdentifier": "39522", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kokubo, Hisashi"}], "nameIdentifiers": [{"nameIdentifier": "36084", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "80397091", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=80397091"}]}, {"creatorNames": [{"creatorName": "Ueno, Kazuhide"}], "nameIdentifiers": [{"nameIdentifier": "37497", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "30637377", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=30637377"}]}, {"creatorNames": [{"creatorName": "Watanabe, Masayoshi"}], "nameIdentifiers": [{"nameIdentifier": "19251", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "60158657", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=60158657"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2022-05-24"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Mizuno_photo-morphology change_R1.pdf", "filesize": [{"value": "1.1 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1100000.0, "url": {"label": "Mizuno_photo-morphology change_R1.pdf", "url": "https://ynu.repo.nii.ac.jp/record/11258/files/Mizuno_photo-morphology change_R1.pdf"}, "version_id": "c83ca952-908c-48fb-bd03-3c81303de997"}, {"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2022-05-24"}], "displaytype": "detail", "download_preview_message": "", "file_order": 1, "filename": "Mizuno_photo-morphologyl change_SI_R2.pdf", "filesize": [{"value": "1.0 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1000000.0, "url": {"label": "Mizuno_photo-morphologyl change_SI_R2.pdf", "url": "https://ynu.repo.nii.ac.jp/record/11258/files/Mizuno_photo-morphologyl change_SI_R2.pdf"}, "version_id": "e629598c-5306-41f6-8017-63786f2d5e47"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "atomic force microscope", "subitem_subject_scheme": "Other"}, {"subitem_subject": "block copolymer", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ionic liquid", "subitem_subject_scheme": "Other"}, {"subitem_subject": "microphase-separated structure", "subitem_subject_scheme": "Other"}, {"subitem_subject": "photoresponsiveness", "subitem_subject_scheme": "Other"}, {"subitem_subject": "sol–gel transition", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Direct Observation of Photo-Induced Reversible Sol-Gel Transition in Block Copolymer Self-Assembly Containing an Azobenzene Ionic Liquid", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Direct Observation of Photo-Induced Reversible Sol-Gel Transition in Block Copolymer Self-Assembly Containing an Azobenzene Ionic Liquid"}]}, "item_type_id": "2", "owner": "3", "path": ["1009"], "permalink_uri": "http://hdl.handle.net/10131/00013917", "pubdate": {"attribute_name": "公開日", "attribute_value": "2021-06-04"}, "publish_date": "2021-06-04", "publish_status": "0", "recid": "11258", "relation": {}, "relation_version_is_last": true, "title": ["Direct Observation of Photo-Induced Reversible Sol-Gel Transition in Block Copolymer Self-Assembly Containing an Azobenzene Ionic Liquid"], "weko_shared_id": 3}
Direct Observation of Photo-Induced Reversible Sol-Gel Transition in Block Copolymer Self-Assembly Containing an Azobenzene Ionic Liquid
http://hdl.handle.net/10131/00013917
http://hdl.handle.net/10131/000139177881e223-6a48-497c-ae1a-a114e06f606a
名前 / ファイル | ライセンス | アクション |
---|---|---|
Mizuno_photo-morphology change_R1.pdf (1.1 MB)
|
|
|
Mizuno_photo-morphologyl change_SI_R2.pdf (1.0 MB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2021-06-04 | |||||
タイトル | ||||||
タイトル | Direct Observation of Photo-Induced Reversible Sol-Gel Transition in Block Copolymer Self-Assembly Containing an Azobenzene Ionic Liquid | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | atomic force microscope, block copolymer, ionic liquid, microphase-separated structure, photoresponsiveness, sol–gel transition | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Mizuno, Haruna
× Mizuno, Haruna× Hashimoto, Kei× Shigenobu, Keisuke× Kokubo, Hisashi× Ueno, Kazuhide× Watanabe, Masayoshi |
|||||
著者所属 | ||||||
Department of Chemistry and Life Science Yokohama National University | ||||||
著者所属 | ||||||
Institute of Advanced Sciences Yokohama National University | ||||||
著者所属 | ||||||
Department of Chemistry and Life Science Yokohama National University | ||||||
著者所属 | ||||||
Department of Chemistry and Life Science Yokohama National University | ||||||
著者所属 | ||||||
Department of Chemistry and Life Science Yokohama National University | ||||||
著者所属 | ||||||
Institute of Advanced Sciences Yokohama National University | ||||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Using atomic force microscopy, the photo-induced reversible changes in a block copolymer self-assembly containing an azobenzene ionic liquid, which undergoes sol–gel transition is directly observed. This is the first report on the sol–gel transition of an ABA-type block copolymer consisting of upper critical solution temperature (UCST)-type A blocks in a photoresponsive ionic liquid mixture. The sol–gel transition is accompanied by an order-to-disorder structural change, which subsequently induces a change in the ionic conductivity. Surprisingly, the photo-induced ionic conductivity and rheological changes occurs rapidly (≈30 s) despite the dense (≈80 wt%) polymeric system. The rapid structural change is probably attributable to the fast diffusion of the ionic liquid. | |||||
書誌情報 |
Macromolecular rapid communications 巻 42, p. 2100091, 発行日 2021-05-24 |
|||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 15213927 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11625232 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1002/marc.202100091 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
出版者 | ||||||
出版者 | Wiley | |||||
関係URI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/marc.202100091 | |||||
関連名称 | https://doi.org/10.1002/marc.202100091 |